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Luperox® for Polypropylene Modification

Viscosity Modification

Isotactic polypropylene is a semi-crystalline polymer.  Free radicals generated using Luperox® organic peroxides degrade the polypropylene backbone via beta-scission. This chemical process is used to adjust the melt flow, grade, and to narrow molecular weight distribution.  This operation is commonly called "vis breaking" or "PP controlled rheology."

 

The organic peroxide can be dry-blended with PP in the hopper of an extruder or injected in the extruder throughout several zones as:

  • a liquid (pure or diluted in a solvent)
  • a solid (peroxide + PP carrier)

Grafting

Peroxide is also useful for grafting maleic anhydride onto PP.  These grafted polymers are useful for:

  • Tie layers
  • Glass and filler
  • Printability and paintability
  • Increased compatibility with other homopolymers

 

Mechanism

The modification of polypropylene is achieved in a 3 step process:

1. Initiation: Free radical formation by thermal decomposition of organic peroxide

Breaking mechanism step 1

2. Macro radical formation: transfer of alkoxy radical to PP backbone

Breaking mechanism step 2

3. Beta scission: Macro radical rearrangement leading to chain scission

Breaking mechanism step 3

The macro radical can then be transferred to another PP chain.

Selection

For the selection of the right organic peroxide and its concentration, the following parameters need to be considered:

  • Technology of injection (liquid or solid)
  • Extruder temperature
  • Extruder residence time
  • Residues in the final resin and food-contact regulations
  • PP characteristics before degradation (homo, copolymer or heterophasic copolymer, MFI, additives type and level)
  • Impact on mechanical properties

 

Generally the extruder residence time is 20-50 seconds and processing temperature is between 200 and 240°C.

Melt flow modification

The chart shows how Luperox® 101 pure peroxide liquid can quickly alter the melt rheology of polypropylene. Accurate metering can be difficult, therefore a dilute form of the peroxide in a solvent or dispersed on a solid is recommended.

Luperox for PP Modification

Grafting

Efficient grafting of maleic anhydride by reactive extrusion can be achieved while also changing the melt rheology of the polypropylene.  This same performance is available with pure liquid Luperox® 101 or the various solvent-added and powder formulations.

Luperox for PP Grafting

Formulations for PP Modification

Luperox® 101 can be used as a technically pure liquid, a dilution in a solvent, or dispersed on granular or powder polypropylene.

Find the right product for your application!

Contact the Luperox® salesperson in your region to learn more

North America

Mike SAUERWALD
Senior Marketing Specialist
900 First Avenue King of Prussia, PA

Central America

Monserrat ALVAREZ
Sales Manager
Arkema Mexico SA de CV
Gustavo Baz 2160 - 3, La Loma, Tlalnepantla, Mexico 54070

South America

Felipe MEDEIROS
Business Unit Manager
Arkema Quimica LTDA
Avenida Ibirapuera 2033 4° Andar - Bairro Moema CEP 04029-901 SÃO PAULO (SP) BRASIL

Europe and Africa

Vincent MENENTEAU
Business Manager
ARKEMA FRANCE
420 rue d'Estienne d'Orves 92705 Colombes Cedex FRANCE

India

Champak HAZARIKA
Sales Manager
Arkema Peroxides India Private Ltd
1st Floor, Balmer Lawrie House 628, Anna Salai, Teynampet, Chennai (Madras), India 600 018

Southeast Asia

Desmond FOONG KAR MUN
Regional Manager
ARKEMA PTE Ltd.
10 Science Park Rd #01-01A, The Alpha, Singapore Science Park II, Singapore 117684

Far East

Jonathan CHANG
Greater China Sales Director
Arkema Changshu Chemical Co Ltd
7F Block 1, Life Hub@Daning 1868 Gonghexin Rd. Shanghai 20072 CHINA

Middle East

Gabriele MALCANGIO
Sales Manager
ARKEMA FRANCE, Middle East Office
Unit 2801 Indigo Icon Tower, Dubai UAE